By Victor H. Agreda
Amazing a stability among uncomplicated chemistry and chemical engineering, this up to date reference discusses very important features of acetic acid and its significant derivatives, together with chemistry, equipment of education and manufacture, and synthesis, in addition to present and rising downstream technologies.;The e-book presents accomplished actual estate information for compounds and their separation, together with acetic acid-water separation. Describing 5 different types of recommendations for the manufacture of acetic acid, it: examines thermophysical homes and aqueous recommendations, with designated reasons of mathematical types and correlations; provides a serious research of estate; outlines production expenditures and comparable financial components; experiences the functions of acetic acid and derivatives; covers the chemistry and education of the derivatives; elucidates contemporary themes reminiscent of deicers, esters and new esterification applied sciences.
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Additional resources for Acetic Acid and its Derivatives (Chemical Industries)
However, there are several references to the production of acetic acid from ethanol in the liquid or gas phase. Direct ethanol oxidation (liquid phase) is reported to give acetic acid (90% yield) in the presence of acetaldehyde, oxygen (air), acetic acid solvent, and cobalt acetate catalyst at 60115°C and 1550 psig . A modification of this process reports increased amounts of ethanol can be used with the incorporation of methyl ethyl ketone in the reaction mixture; higher temperatures and pressures are also apparently involved .
S. Patent 3,240,805 to Halcon International (March 15, 1966). 3. Japanese Patent 41-17456 to Halcon International (Oct. 4, 1966). 4. French Patent 1,568,742 to IFP (May 30, 1969). 5. French Patent 2,073,229 to IFP (Nov. 5, 1971). 6. Japanese Kokai 7,106,763 to Japan Catalytic (Feb. 20, 1971); Chem. , 75, 63163. 7. , 77, 33958. 8. European Patent Application 162,263 to National Distillers (Nov. 27, 1985). 9. Belgian Patent 776,752 to National Distillers (June 15, 1972). 10. , Eur. Pat. K. (Oct. 2, 1985).
Texas A&M, College Station, TX, 1984, p. 71. 15. Brownstein, A. S. , Tulsa, OK, 1972, p. 300. 16. Miller, S. , Acetylene, Its Properties, Manufacture, and Uses, Vol. 2, Academic Press, New York, 1966, p. 134. 17. Lowenheim, F. , and Moran, M. , Wiley-Interscience, New York, 1975, pp. 23. 18. Miller, S. , Acetylene, Its Properties, Manufacture, and Uses, Vol. 2, Academic Press, New York, 1966, p. 148. 19. , in Ethylene and Its Industrial Derivatives (S. A. ), Ernest Benn, London, 1969, pp. 767770.